In both cases, isotope compositions referred to 2H and 18O highlight a δ 2H enrichment for some groundwater samples taken in wells, located near leachate storage wells. The paper shows two case studies, in central and southern Italy, where potential contamination phenomenon of groundwater under municipal solid waste landfills occurred. Deuterium ( 2H) and oxygen ( 18O) isotopes have successfully used to identify groundwater contamination phenomena if submitted to interactions with municipal solid waste landfills leachate, with a significant organic amount. During recent years, the use of stable isotopes as environmental tracers to identify groundwater contamination phenomena has found application to environmental engineering. Groundwater contamination due to municipal solid waste landfills leachate is a serious environmental threat.
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